PSI - Issue 5
L. ALEXANDRESCU et al. / Procedia Structural Integrity 5 (2017) 675–682 Laurentia Alexandrescu / Structural Integrity Procedia 00 (2017) 000 – 000
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- Oxidation of graphite nanoparticle surface in order to activate it is a method of improving wettability and chemical bonding of graphite/polymer matrix. - Polyamide and oxidized graphite were mechanically mixed in a Brabender Plasti-Corder PLE-360 at 10-120 rotations/min, for 2 min. at 230 0 C to melt the plastomer, mixed for 3 min. at 240 0 C and 2 min. at 200 0 C for homogenisation. - The nanocomposites polyamide/oxidized graphite were characterized by scanning electron microscopy (SEM) and Fourier transformation infrared spectrum (FT-IR) and physico-mechanical. - Graphene oxide concentrations higher than 1% lead to decreases in shock resistance values and tensile strength values. This leads to the conclusion that percentages in the 0.1-1% range lead to maximum values of physical mechanical parameters.
Acknowledgements This research was financed through PN-III-P2-2.1-PTE-2016, project: “ New nanostructured polymeric composites for centre pivot liners, centre plate and other components for the railway industry - RONERANANOSTRUCT ” supported by UEFISCDI Romania.
References
Balandin, A.A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., Lau, C.N., 2008. Superior Thermal Conductivity of Single-Layer Graphene. Nano Lett., 8, 902 – 907. Bhattacharya, M., 2016. Polymer Nanocomposites — A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers. Materials, 9, 262-297. Biswas, M.; Ray, S.S., 2001. Recent progress in synthesis and evaluation of polymer-montmorillonite nanocomposites. Adv. Polym. Sci., 155, 167 – 221. Bitinis, N., Hernandez, M., Verdejo, R., Kenny, J.M., Lopez-Manchado, M.A.,2011. Recent Advances in Clay/Polymer Nanocomposites. Adv. Mater., 23, 5229 – 5236. Brune, D.A., Bicerano, J., 2002. Micromechanics of nanocomposites: Comparison of tensile and compressive elastic moduli, and prediction of effects of incomplete exfoliation and imperfect alignment on modulus. Polymer 43, 369 – 387. Bunch, J.S., Alden, J.S., Zande, A.M., Parpia, J.M., Craighead, H.G., McEuen, P.L., 2008. Impermeable Atomic Membranes from Graphene Sheets. Nano Lett., 8, 2458 – 2462 Chen, B., Evans, J.R.G. 2006. Elastic moduli of clay platelets. Scripta Mater. 54, 1581 – 1585. Chow W. S., Mohd Ishak Z. A., Karger-Kocsis J., et all, 2003. Compatibilizing effect of maleated polypropylene on the mechanical properties and morphology of injection molded polyamide 6/ polypropylene/organoclay nanocomposites. Polymer, 44 , 7427 – 7440 . Das, P., Jani-Markus, S., Malho, B.Z., Klemradt, U., Walther, A., 2013. Facile Access to Large-Scale, Self-Assembled, Nacre-Inspired, High Performance Materials with Tunable Nanoscale Periodicities. ACS Appl. Mater. Interfaces, 5, 3738 – 3747. Erdmann E., Dias M. L., Pita V. J., Destéfanis H., Monasterio F., Acosta D., 2007. Characterization of HDPE /polyamide&6/nanocomposites using scanning-and transmission electron microscopy. Macromolecular Symposia, 258 , 82 – 89 . Fasolino, A., Los, J.H., Katsnelson, M.I., 2007. Intrinsic ripples in graphene. Nat. Mater., 6, 858 – 861. Geim, A.K., Novoselov, K.S., 2007. The rise of graphene. Nat. Mater., 6, 183 – 191. Hyunwoo, K., Ahmed, A., Macosko, W., 2010. Graphene/Polymer Nanocomposites, Macromolecules, 43 (16), pp 6515 – 6530. Kovtyukhova NI, Ollivier PJ, Martin BR, Mallouk TE, Chizhik SA, Buzaneva EV, et al., 1999. Layer-by-Layer Assembly of Ultrathin Composite Films from Micron-Sized Graphite Oxide Sheets and Polycations. Chemistry of Materials.11:771-8. Lee, C., Wei, X., Kysar, J.W., Hone, J., 2008. Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene. Science, 321, 385 – 388. Lonjon A., Caffrey I., Carponcin D., Dantras E., Lacabanne C., 2013. High electrically conductive composites of Polyamide 11 filled with silver nanowires: Nanocomposites processing, mechanical and electrical analysis. Journal of Non-Crystalline Solids, 376, 199 – 204. Paul, D.R., Robeson, L.M., 2008. Polymer Nanotechnology: Nanocomposites. Polymer, 49, 3187 – 3204. Suter, J.L., Coveney, P.V., Greenwell, H.C., Thyveetil, M.-A., 2007.Large-scale molecular dynamics study of montmorillonite clay: Emergence of undulatory fluctuations and determination of material properties. J. Phys. Chem. C, 111, 8248 – 8259. Ward, I.M., Sweeney, J. 2004. An Introduction to the Mechanical Properties of Solid Polymers; John Wiley: Sussex, UK. Zhang B., Wong J. S-P., Yam R. C-M., Li R. K-Y., 2010. Enhanced wear performance of nylon 6/organoclay nanocomposite by blending with a thermotropic liquid crystalline polymer. Polymer Engineering and Science, 50, 900 – 910.
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