PSI - Issue 28

Angeliki-Eirini Dimou et al. / Procedia Structural Integrity 28 (2020) 1679–1685 Author name / Structural Integrity Procedia 00 (2019) 000–000

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4. Conclusions In the present work, aqueous rGO dispersions were studied with Electrical Impedance Spectroscopy. The aim of the study was to find the appropriate dispersion to be incorporated in a cementitious matrix as a future step. Through the application of EIS, the concentration of rGO and the optimal amount of sonication energy were determined. The results showed that at low rGO concentrations the electrical impedance decreases as sonication energy increases, indicating a better and more uniform dispersion, leading to the formation of conductive networks. In higher rGO concentrations, an increase in sonication energy up to intermediate energy values leads to an increase of the electrical impedance, but a further increase of the applied energy leads to lower values of the impedance. The results indicated that the aqueous solution with rGO concentration level at 0.15 wt% of the binder and at sonication energy of about 60 kJ is appropriate to be used to produce the cementitious composites. Acknowledgements This research has been co‐financed by the European Regional Development Fund of the European Union and Greek national funds through the Operational Program Competitiveness, Entrepreneurship and Innovation, under the call RESEARCH – CREATE – INNOVATE (project code: T1EDK-03069, MIS 5031866, project name: Self-healing and self-sensing nano-composite conservation mortars – acronym: AKEISTHAI). The authors would also like to thank Professor Dimitrios GOURNIS (University of Ioannina, Department of Materials Science & Engineering) for providing the nanomaterials used in the present work as well as Assistant Professor Zoi METAXA for her valuable comments on the mixing technique under the framework of the AKEISTHAI research project. References Baig, Z., Mamat, O., Mustapha, M., Mumtaz, A., Munir, K., Sarfraz, M., 2018. Investigation of tip sonication effects on structural quality of graphene nanoplatelets (GNPs) for superior solvent dispersion. Ultrasonics - Sonochemistry 45 , 133-149. Baomin, W., Shuang, D., 2019. Effect and mechanism of graphene nanoplatelets on hydration reaction, mechanical properties and microstructure of cement composites. Construction and Building Materials 228, 116720. Gao, Y., Jing, H., Chen, S., Du, M., Chen, W., Duan, W., 2019. Influence of ultrasonication on the dispersion and enhancing effect of graphene oxide–carbon nanotube hybrid nanoreinforcement in cementitious composite. Composites Part B 164 , 45-53. Hawreen, A., Bogas, J., Dias, A., 2018. On the mechanical and shrinkage behavior of cement mortars reinforced with carbon nanotubes. Construction and Building Materials 168, 459-470. Konios, D., Stylianakis, M., Stratakis, E., Kymakis, E., 2014. Dispersion behaviour of graphene oxide and reduced graphene oxide. Journal of Colloid and Interface Science 430, 108-112. Liew, K., Kai, M., Zhang, L., 2017. Mechanical and damping properties of CNT-reinforced cementitious composites. Composite Structures 160, 81-88. Madbouly, A., Mokhtar, M., Morsy, M., 2020. Evaluating the performance of rGO/cement composites for SHM applications. Construction and Building Materials 250, 118841. Muthoosamy, K., Manickam, S., 2017. State of the art and recent advances in the ultrasound-assisted synthesis, exfoliation and functionalization of graphene derivatives. Ultrasonics - Sonochemistry 39, 478–493. Peng, H., Ge, Y., Cai, C., Zhang, Y., Liu, Z., 2019. Mechanical properties and microstructure of graphene oxide cement-based composites,. Construction and Building Materials 194, 102-109. Prabavathy, S., Jeyasubramanian, K., Prasanth, S., Hikku, G., Jeen Robert, R., 2020. Enhancement in behavioral properties of cement mortar cubes admixed with reduced graphene oxide. Journal of Building Engineering 28, 101082. Valizadeh Kiamahalleh, M., Gholampour , A., Tran , D., Ozbakkaloglu , T., Losic, D., 2020. Physiochemical and mechanical properties of reduced graphene oxide–cement mortar composites: Effect of reduced graphene oxide particle size. Construction and Building Materials 250, 118832. Vallejo, J., Żyła, G., Fernández-Seara, J., Lugo, L., 2018. Rheological behaviour of functionalized graphene nanoplatelet nanofluids based on water and propylene glycol water mixtures. International Communications in Heat and Mass Transfer 99, 43-53. Wang, D., Zhang, X., Zha, J., Zhao, J., Dang, Z., Hu, G., 2013. Dielectric properties of reduced graphene oxide/polypropylene composites with ultralow percolation threshold. Polymer 54 , 1916-1922. Wang, Q., Wang, J., Lu, C., Liu, B., Zhang, K., Li, C., 2015. Influence of graphene oxide additions on the microstructure and mechanical strength of cement. New Carbon Materials 30, 349-356. Wang, S., Zhang, S., Wang, Y., Sun, X., Sun, K., 2017. Reduced graphene oxide/carbon nanotubes reinforced calcium phosphate cement. Ceramics International 43, 13083–13088. Zare, Y., Rhee, K., Hui, D., 2017. Influences of nanoparticles aggregation/agglomeration on the interfacial/interphase and tensile properties of nanocomposites. Composites Part B 122 , 41-46. Zhang, N., She, W., Du, F., Xu, K., 2020. Experimental Study on Mechanical and Functional Properties of Reduced Graphene Oxide/Cement Composites. Materials 13, 3015. Zhang, W., He, W., Jing, X., 2010. Preparation of a Stable Graphene Dispersion with High Concentration by Ultrasound. The Journal of Physical Chemistry B 114, 10368–10373.

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