PSI - Issue 20
Sharin P.P. et al. / Procedia Structural Integrity 20 (2019) 236–241 Sharin P.P. et al. / Structural Integrity Procedia 00 (2019) 000–000
240
5
4. Conclusion Thin metal-carbide coatings formed on the transition zone consisting of an interacting metal, carbide phases, traces of oxide and graphite during solid-phase contact interaction of diamond with transition metals in the conditions specified in the experiment. Metal-carbide coatings bond strength were determined by shear test: diamond-iron and diamond-chromium contact pairs have the highest contact strength of 24.12 MPa and 6.76 MPa, respectively. The revealed structural-phase features of the transition zone are caused by the difference in the degree of the catalytic effect of metals on the phase transformation of diamond into amorphous carbon. The formation of a durable metal-carbide layer during the contact interaction of diamond with iron and chromium – which essentially is a metallized coating obtained under conditions corresponding to sintering copper-impregnated diamond-containing matrices based on cemented carbide powder mixtures – can be used in a technology development that provides an increased level of diamond retention in composite materials. References Artini, C., Muolo, M.L., Passerone, A, 2012. Diamond-metal interfaces in cutting tools: a review. Journal of Materials Science 47, 3252–64 Cu(Cr)–diamond composite interlayer. Materials Letters 81, 155–157 Hsieh, Y.Z., Lin, S.T., 2001. Diamond tool bits with iron alloys as the binding matrices. Materials Chemistry and Physics 72, 121–125. Huang, Y., Xiao, H., Ma, Zh., Wang, J., Pengzhao, G., 2007. Effects of Cu and Cu/Ti interlayer on adhesion of diamond film. Surf. Coat. Technol. 202, 180–184 Isonkin, A.M., Duda, T.M., Belyavina, N.N., Tkach, V.N., 2013. Vliyanie metallizatsii almazov na strukturoobrazovanie i prochnost kompozitsionnogo materiala. [Effect of diamond plating on the structure and strength of the composite material]. Naukovi praci DonNTU. Seriya «Girnicho-geologichna» 19 146–154. (in Russian) Konovalov, V.A., Tkach, V.N., Shatokhin, V.V., 2009. Razrushenie metallicheskoi svyazki pri vysokoskorostnom tsiklicheskom nagruzhenii almaznogo zerna [The destruction of the metal bond under high cyclic loading of the diamond grains]. Porodorazrushayushiy i metalloobrabatyvayushiy instrument – tekhnika, tekhnologiya ego izgotovleniya i primeneniya: Proceeding of Institute for superhard materials the V.Bakul National Academy of Ukraine 12, 504–508. (in Russian) Kushatlova, I.P., Stasyuk, L.F., Uskokovich, D.P., Radich, S.M., Ristich, M.M., 1984. Hardening of a metal matrix by titanium carbide obtained by reaction in the diamond-titanium-nickel system. Glasnik hemijskog drushtva Beograd. Bulletin De La Societe Chimique Boegrad 49, 555– 561 Loktyushin, V.A., Gurevich, L.M., 2009. Poluchenie nanotolshinniykh metalicheskikh pokriytiy na sverkhtverdiykh materialakh metodom termodiffuzionnoi metallizatsii [Obtaining of nano-sized metal coverings on superhard materials by method thermodiffusion metallization]. Izvestia VSTU 11, 50–54. (in Russian) Margaritis, D.-P., 2003. Interfacial bonding in metal-matrix composites reinforced with metal-coated diamonds. Nottingham, PhD thesis, pp.345 Naidich, Yu.V., Kolesnichenko, G.A., 1967. Vzaimodeistvie metallicheskikh splavov s poverkhnostiyu almaza i grafita [The interaction of metal melts the surface of diamond and graphite]. Naukova Dumka, Kiev, pp89. Novikov, N.V., Bondarenko, N.A., Kulik, O.G., Mechnik, V.A., Zhukovsky, A.N., 2004. Fiziko-matematicheskoe modelirovanie prosetsev spekaniya mnogokomponentnykh almazosoderzhashikh kompozitsii. 2. Fiziko-khimicheskie osobennosti formirovaniya struktury i svoistv. [Physical and mathematical modeling of diamond sintering multicomponent compositions. 2. Physical and chemical features of formation of structure and properties]. Physical Mesomechanics 7, 79–87. Nozhkina, A.V., 1988. Vliyanie metallov na fazovoe prevrashenie almaza v grafit [Influence of metals on phase transformation of diamond in graphite]. Journal of Superhard Materials 3, 11–15. Qiu, W.Q., Liu, Z.W., He, L.X., Zeng, D.C., Mai, Y.-W., 2012. Improved interfacial adhesion between diamond film and copper substrate using a Cu(Cr)–diamond composite interlayer. Materials Letters 81, 155-157. Semenov, A.P., Pozdnyakov, V.V., Kraposhina, L.B., 1974. Friction and contact interaction of graphite and diamond with metals and alloys. Nauka, Moscow, pp.110. Sharin, P.P., Yakovleva, S.P., Gogolev, V.E., Popov, V.I., 2016. Stroenie I prochnost perekhodnoi zony pri tverdofaznom vysokotemperaturnom vzaimodeistvii almaza s karbidoobrazuyuwimi metallami – kromom I kobaltom [Structure and strength of the transition zone in solid-phase high-temperature interaction of diamond with carbide-forming metals - chromium and cobalt]. Perspektivnye Materialy 7, 47–60 Stasyuk, L.F., Kushatlova, I.P., Uskokovich, D.P., Krstanovich, I., Radich, S.M., Ristich, M.M., 1984. Reactive sintering in the diamond titanium-chromium system under high pressure. Glasnik hemijskog drushtva Beograd. Bulletin de la societe chimique Beograd 49, 563–569 Tillmann, W., Ferreira, M., Steffen, A., Rüster, K., Möller, J., Bieder, S., Paulus, M., Tolan, M., 2013. Carbon reactivity of binder metals in diamond–metal composites – characterization by scanning electron microscopy and X-ray diffraction. Diamond & Related Materials 38, 118– 123. Tillmann, W., Tolan, M., Lopes-Dias, N. F., Zimpel, M., Ferreira, M., Paulus, M., 2015. Influence of chromium as carbide forming doping element on the diamond retention in diamond tools. In: Proceedings of the International Conference on Stone and Concrete Machining (ICSCM) Bochum, Germany 3, 21–30.
Made with FlippingBook - Online catalogs